[7e93c] @R.e.a.d@ The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications - Gerard Van Koten ^P.D.F!
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The seemingly simple tridentate ligand design, one that is now known as the “pincer,” has gained increasing importance in metal–ligand chemistry and in other applications as diverse as organic synthesis, catalysis, and materials science. This chapter describes the historical context in which the pincer ligand platform developed and sketches how shaw’s research played a crucial early role.
Abstract during the past 40 years, the monoanionic, tridentate ligand platform that has been named “pincer” has established itself as a privileged ligand in a variety of research and application areas. Exciting discoveries with ncn and pcp-pincer metal complexes in the late 1970s created a firm basis for the tremendous development of thefield.
Pincer complexes are formed by the binding of a chemical structure to a metal a donor atom in the side arms have been known as a privileged pincer platform.
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The monoanionic pincer–metal platform: which is a well-established privileged ligand with a proven potential in a wide range of applications.
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Com: organometallic pincer chemistry (topics in organometallic chemistry, mono-anionic ece-pincer ligand - a versatile privileged ligand platform: general behavior of pcp and pcn pincer ligands of late metal complexes.
The privileged pincer-metal platform coordination ~ (2016) [원서] (topics in organometallic chemistry 54) gerard van koten, robert a gossage (eds.
A pgep pincer-type germylene, ge(nch2ptbu2)2c6h4, which contains two phosphane (a) the privileged pincer–metal platform: coordination chemistry.
The monoanionic pincer–metal platform: a scaffold for meeting challenges in catalysis and materials research. In 1976, shaw and moulton reported on a pincer–nickel compound with the nickel atom held in place by a monoanionic, terdentate pcp ligand. 1 at that time these authors could not have imagined that 35 years later a dalton transactions themed issue would be devoted to papers describing novel developments in organometallic chemistry featuring the pincer platform as a crucial factor.
Since the first pincer complexes were reported in the 1970s, this class of materials has greatly expanded and now the ligand framework is often referred to as one of the “privileged” classes of metal binding agents.
Privileged metal-ligand cooperating pincer platforms in first-row de-/ hydrogenation catalysis. Over the last two decades several pincer platforms were in- troduced.
The privileged pincer metal platform coordination chemistry applications book description the series topics in organometallic chemistry presents critical overviews of research results in organometallic chemistry.
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설명 [원서] (topics in organometallic chemistry 54) gerard van koten, robert a gossage (eds. ) - the privileged pincer-metal platform coordination ~ (2016).
Remarkably, there are several reports in literature using pincer-type metal these complexes might even be considered a privileged family of catalysts [262, 263 representing versatile platform molecules for the bulk industry [751,75.
Gerard van koten: the mono-anionic ece-pincer ligand - a versatile privileged ligand platform: general considerations. - elena poverenov, david milstein: non-innocent behavior of pcp and pcn pincer ligands of late metal complexes.
The use of xcx‐aryl pincer metal complexes as catalysts started immediately after their discovery in 1976. Nowadays pincer metal complexes are commonly used as a new platform for the development.
Recent advances in alkane dehydrogenation catalyzed by pincer complexes.
The privileged pincer metal platform coordination chemistry applications. Author: gerard van koten,robert a gossage: publsiher: springer: total pages: 374: release.
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